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The code solves for the number of voxels associated with each ion in the dictionary. This is done by mapping the intensity of the channel and the total intensity for each voxel ( Voxel ) within the defined kernel. The voxel count is converted to a relative intensity (the size of the impulse response of the kernel is converted into a relative intensity), and the relative intensity is used as the weighting factor for each ion. The number of voxels, is then divided by the total number of voxels contained in the kernel, to determine the average number of voxels associated with each ion.
There is no distinction between the fractional and absolute concentration. The vwrfit function therefore calculates the total error for the best estimated fractional concentration (this is used in the vwr errors =
When using this mode for new aerosol data, a reasonable estimation of the total error for an average concentration, can be made by calculating the average concentration and multiplying it by the error factor of 2.0. This factor is given for LOD blank, system blank, and the standard deviation for blank subtraction of the calibration curve.
The standard deviation for the blank subtraction is the standard deviation for the calibration curve. However, if there is significant deviation of the calibration curve from linearity, the standard deviation for the calibration curve is best used to calculate the final total error. d2c66b5586